Search results for "Melting and crystallization process"

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Thermal behavior of ethylene copolymers with di- and tri-alkenylsilsesquioxane comonomers synthesized by post-metallocene catalysts

2020

AbstractThis paper reported thermal properties of ethylene copolymers with di- and tri-alkenylsilsesquioxanes (POSS) synthesized by bis(phenoxy-imine) Ti, Zr, V, and V salen-type complexes. Ethylene copolymers with multi-alkenyl POSS obtained by such complexes contain multi-alkenyl POSS incorporated into the polymer chain as a side group. They were characterized by different thermal behavior depending on the kind of multi-alkenyl POSS comonomer, and type of the catalyst used, as well as polymerization conditions and thus the structure of the copolymer chain. Ethylene/POSS copolymers differed in incorporation of POSS into the polymer chain, content of specific unsaturation groups, and molecu…

Materials scienceEthylene02 engineering and technology01 natural scienceschemistry.chemical_compoundEthyleneCopolymerThermal stabilityPhysical and Theoretical ChemistryPendant groupchemistry.chemical_classificationComonomerCopolymersMelting and crystallization processPolymerThermal stability021001 nanoscience & nanotechnologyCondensed Matter Physics010406 physical chemistry0104 chemical scienceschemistryPolymerizationChemical engineeringMulti-alkenyl polyhedral oligomeric silsesquioxanes (POSS)0210 nano-technologyMetalloceneJournal of Thermal Analysis and Calorimetry

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